Proving that its sum is π2/6 is quite a bit harder. One can do it by defining a function f (x) = 0 if -π ≤ x ≤ 0 and x2 if 0 < x ≤ π and expanding it as a Fourier series, though that is not how Euler originally proved it!
Finding its limit is rather tricky. Experimenting with Maple suggests that 3/5 is a good guess.
A standard way of dealing with recurrence relations like this one is to guess a solution of the form an = μn which in this case gives μ = 1 or -2/3 and the general solution is then of the form an= A.1n + B.(-2/3)n for some constants A and B.
Choosing A and B to give the correct answer for a1 and a2 gives the formula an = 3/5 + 9/10 × (-2/3)nand so as n→ ∞ we have (an)→ 3/5.