ii) This is case (c): rotation by π about the z-axis followed by reflection in the (x, y)-plane.
iii) Products of rotations are always rotations since SO(3) is a subgroup and so we have case (b).
Seeing what the axis is can be rather tricky. For example, rotation (by π/2 anticlockwise) about the x-axis, followed by rotation about the y-axis followed by rotation about the z-axis is rotation by π/2 about the y-axis.
You can see this a different way by observing that the symmetries mapping one square to the other can be obtained by composing (say) the translation by the symmetries that map the second square to itself. That is TAX∘D4, where the dihedral group acts fixing the centre of XYZT.